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31.
土壤中石油污染物微生物降解及其降解去向 总被引:9,自引:0,他引:9
通过多因素对比预实验,将筛选出的7个石油烃降解的主要影响因素以正交表方法组合起来,对其进行了实验研究。探讨了石油迁移转化对于各种土壤物理化学条件及其他环境因素改变的敏感程度,并找出了各主要影响因素的重要性和最佳水平;测定了土壤中所存在的石油污染物在生物降解作用下的后期产物,研究了不同条件下的样品残留污染物组分之间的差异。影响土壤中石油烃类降解的主要因素有土壤石油污染强度、营养物(NH4NO3、K2HPO4)、氧化剂(3%H2O2溶液)、表面活性剂(TW80)、温度、土壤含水率和土壤透气性;在降解的不同阶段,各个因素的重要性以及最佳水平会发生相应的变化;在生物降解后期,土壤中残留的石油污染物主要是正构和异构烷烃;正构烷烃的色谱图由原来的对称钟形变为左陡右缓的偏钟形;异构烷烃所占比重增大,正十五烷和正二十一烷之间的谱图基线被明显抬高。 相似文献
32.
Beatriz O. Hincapie Luis J. Garces Sinue Gomez Ruma Ghosh Steven L. Suib 《Catalysis Today》2005,110(3-4):323
Copper containing faujasite has been successfully prepared for the first time using a direct synthesis method. Faujasite type zeolite can be prepared in the presence of copper species by tuning the synthesis conditions. Ammonium hydroxide was used to form a copper complex that was later mixed with the reacting gel. Sodium is required to obtain copper faujasite. The complete elimination of sodium ions from the starting gel produces amorphous material. Crystallization took place at 358 K for 11 days. Crystallization temperature of 373 K produces ANA type zeolite as an impurity. Increasing by two times the amount of copper complex added to the reacting gel increases the crystallization time of Cu-FAU from 11 to 20 days (the crystallization rate decreases). The copper containing faujasite obtained was characterized by XRD, FESEM, EDX, EPR, FT-IR, TPR, and BET. According to the XRD pattern only FAU type zeolite was obtained. According to TPR experiments, the reduction temperature for Cu2+ ions present in Cu-FAU prepared by direct synthesis was 70 K more than for Cu-FAU prepared by ion-exchange. This difference can be due to the different location of the copper ions in the supercages or in the sodalite cages of the faujasite. 相似文献
33.
绿色包装材料——生物降解塑料 总被引:8,自引:4,他引:4
对绿色包装材料-生物降解塑料的降解机理、特点,国内外研究现状和进展及存在的问题和发展前景进行了介绍。 相似文献
34.
35.
Michael Adam Steve Comfort Daniel Snow David Cassada Matthew Morley Wilson Clayton 《Canadian Metallurgical Quarterly》2006,132(12):1580-1588
Years of wastewater discharge at the Department of Energy’s Pantex Plant have contaminated the vadose zone and underlying perched aquifer with hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX). Because the vadose zone is acting as a continual source of groundwater contamination, removing RDX from the unsaturated zone is paramount to prevent further contamination. We determined the efficacy of ozone to degrade and mineralize RDX. Solution experiments showed that ozone (27?mg?L?1; 150?mL?min?1) was effective in mineralizing 80% of the RDX (30?mg?RDX?L?1) provided that some Pantex soil was present to buffer the solution pH. Soil columns treated with ozone produced 50% RDX mineralization within 1 day and >80% within 7 day. Experiments designed to evaluate aerobic biodegradation following partial ozonation of a RDX solution showed that ozone-generated RDX products were much more biodegradable than untreated controls in aerobic microcosms (35 versus <0.3% cumulative mineralization). These results support the use of ozone as a remedial treatment for the contaminated vadose zone at the Pantex facility. 相似文献
36.
Baak K. Taeli 《Lakes & Reservoirs: Research and Management》2006,11(3):149-168
Lake Mogan, located in the steppes of central Anatolia, is a vital Turkish ecological system, in terms of its water resources, flora and fauna. The lake also is a unique recreational area for Ankara, the capital of Turkey. However, the lake is currently threatened by severe pollution, being under the risk of serious degradation because of (i) uncontrolled urbanization; (ii) point and non‐point source pollution; (iii) inefficient sewerage systems; (iv) sediment transportation and pollution via influent creeks to the lake; (v) uncontrolled soil erosion in its drainage basin; (vi) inappropriate flood control measures; and (vii) severe degradation of the natural wetlands within its drainage basin. This study evaluates the influence of its influent creeks on the water quality of Lake Mogan, mainly because the creeks are believed to be responsible for the major pollutant load reaching the lake, and because the extensive database documenting this situation has not previously been critically evaluated. Accordingly, this study reviews (i) change in the water quality of Lake Mogan between 1993 and 2002; (ii) the water quality classification of the major influent creeks feeding Lake Mogan; and (iii) the influence of the influent creeks on the water quality of the lake between 1993 and 2004. 相似文献
37.
水生生物环境诊断(AOD)技术应用研究 总被引:4,自引:0,他引:4
介绍一种新型的毒性试验方法——水生生物环境诊断(AOD)技术,该方法将冷冻浓缩和生物测试技术有机地相结合,较好地解决了低毒性水体的毒性测试问题。应用本项技术以红鳍鱼为受试生物,分别对湖北武汉马伧湖、墨水湖、广东深圳河、长江干流寸滩等几个断面、丹江口水库白河、丹江河口、老灌河等不同水体进行AOD测试,所得48hr-LC\-50结果与实际水质状况基本相符。 相似文献
38.
We define the hazardous waste management problem as the combined decisions of selecting the disposal method, siting the disposal plants and deciding on the waste flow structure. The hazardous waste management problem has additional requirements depending on the selected disposal method. In this paper we focus on incineration, for which the main additional requirement is to satisfy the air pollution standards imposed by the governmental restrictions. We propose a cost-based mathematical model in which the satisfaction of air pollution standards is also incorporated. We used the Gaussian Plume equation in measuring the air pollution concentrations at population centers. A large-scale implementation of the proposed model within Turkey is provided. 相似文献
39.
唐德修 《成都纺织高等专科学校学报》2007,24(3):13-15
科学焚烧处理垃圾法具有占地少,场地易选择,时间短,减量化显著,无害化彻底以及回收余热供发电供热等优点.其处理设备和控制系统是保证科学焚烧处理垃圾成功,并带来巨大经济效益的关键.鉴于此,文章对科学焚烧垃圾系统设计作了比较详细的介绍. 相似文献
40.
This study focuses on how to assess the optimal environmental investment decisions under economic and ecological uncertainty, and establishes the continuous time model using the real option approach to optimize environmental pollution policy. Unlike traditional cost benefit analysis, this work extends the model of [Pindyck, R.S., 2002. Optimal timing problems in environmental economics. Journal of Economic Dynamics and Control 26(9–10), 1677–1697], and attempts to identify the storage threshold of pollution stocks and the optimal timing for implementing environmental pollution decisions. 相似文献